Extraction spectrophotmetric determination of rare earth with trioctylethylammonium bromide and Xylenol Orange
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Solid Phase Spectrophotometric Determination Of Cobalt By Xylenol Orange
A simple and sensitive solid phase spectrophotometric method for the determination of cobalt is proposed based on the reaction between cobalt and xylenol orange (XO). The reaction product is fixed on the anionic exchanger resin sephadex QAE A-25 at pH= 5. The optical absorbance of the anionic gel like resin, packed in a 1.00 mm cell is directly measured at 588.0 nm. The linear range of calibrat...
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Trace amounts of thallium(I) can be determined using adsorptive cathodic stripping voltammetry in the presence of Xylenol Orange (XO). The reduction current of the thallium(I)-XO complex ion was measured by square-wave cathodic stripping voltammetry. The peak potential was at -0.44 V vs. Ag/AgCl. The effect of various parameters (pH, ligand concentration, accumulation potential and collection t...
متن کاملSimultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares
A partial least squares (PLS) calibration model was developed for the simultaneous spectrophotometricdetermination of Pb (ΙΙ), Cu (ΙΙ) and Ni (ΙΙ) using xylenol orange as a chromogenic reagent. The parameterscontrolling behavior of the system were investigated and optimum conditions were selected. The calibrationgraphs were linear in the ranges of 0.0–9.091, 0.0–2.719 and 0.0–2.381 ppm for lead...
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The ferric-xylenol orange (FOX) method for measurement of hydroperoxides is based on a technique that employs reduction of peroxides in an acidic condition by Fe2+ and formation of the colored ferric-xylenol orange (XO/Fe3+) product with a peak at 560 nm. The 560 nm absorbance peak of XO/Fe3+ shifts to a 610 nm peak with high absorption intensity in the presence of phosphatidylcholine. This is ...
متن کاملDetermination of hydroperoxides in aqueous solutions containing surfactants by the ferrous oxidation-xylenol orange method.
Some surfactants widely used as additives in food, pharmaceuticals, and cosmetic formulations are susceptible to peroxidation resulting in accumulation of hydroperoxides (HP). Our investigation was aimed to study the possible influence of different surfactants on the proportionality and reproducibility of the ferrous oxidation-xylenol orange method developed originally for the determination of ...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1976
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.25.680